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osunpk

osunpk

Since 2008 I have served as the Precision Nutrient Management Extension Specialist for Oklahoma State University. I work in Wheat, Corn, Sorghum, Cotton, Soybean, Canola, Sweet Sorghum, Sesame, Pasture/Hay. My work focuses on providing information and tools to producers that will lead to improved nutrient management practices and increased profitability of Oklahoma production agriculture

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One Well-Timed Shot: Rethinking Split Nitrogen Applications in Wheat production

Brian Arnall, Precision Nutrient Management Specialist
Samson Abiola, PNM Ph.D. Student.

Nitrogen is the most yield limiting nutrient in wheat production, but it’s also the most unpredictable. Apply it too early, and you risk losing it to leaching or volatilization before your crop can use it. Apply it too late, and your wheat has already determined its yield potential; you’re just feeding protein at that point. For decades, the conventional wisdom has been to split nitrogen applications: put some down early to get the crop going, then come back later to apply again. But does splitting actually work? And more importantly, when is the optimal window to apply nitrogen if you want to maximize both yield and protein quality? We spent three years across different Oklahoma locations testing every timing scenario to answer these questions.

How We Tested Every Nitrogen Timing Scenario in Oklahoma Wheat

Between 2018 to 2021, we conducted field trials at three Oklahoma locations, including Perkins, Lake Carl Blackwell, and Chickasha, representing different soil types and growing conditions across the state. We tested three nitrogen rates: 0, 90, and 180 lbs N/ac, applied as urea at five critical growth stages based on growing degree days (GDD). These timings were 0 GDD (preplant, before green-up), 30 GDD (early tillering), 60 GDD (active tillering), 90 GDD (late tillering, approximately Feekes 5-6), and 120 GDD (stem elongation, approaching jointing). We also compared single applications at each timing against split applications, where half the nitrogen (45 lbs N ac-1) went down preplant, and the other half was applied in-season (45 lbs N ac-1).

The Sweet Spot: Yield and Protein at the 90 lbs N/ac Rate

Across all site-years, at the 90 lbs N/ac rate, timing had a significant impact on both yield and protein. The highest yields came from the 30 and 90 GDD timings, producing 62 to 66 bu/ac, with 60 GDD reaching the peak (Figure 1). Protein at these early timings stayed relatively modest at 13%. The 90 GDD timing delivered 62 bu/ac with 14% protein matching the yield of the 30 GDD application but pushing protein a percentage higher (Figure 2). The real problem appeared at 120 GDD. Delaying application until stem elongation dropped yields to just 49 bu/ac, even though protein climbed to 15%. That’s a 13 bushel penalty compared to the 90 GDD timing. At current wheat prices per bushel, that late application may cost farmers over $100 per acre in lost revenue. By 120 GDD, the crop has already determined its yield potential tillers are set, head numbers are locked in and nitrogen applied at this stage can only be directed toward protein synthesis, not building more yield components.

Figure 1: Grain yield response to nitrogen rate and application timing across three nitrogen rates: 45-45 lbs N/ac 90 lbs N/ac, and 180 lbs N/ac averaged across eight site-years in Oklahoma. Nitrogen was applied at five timings: 0, 30, 60, 90, and 120 GDDs. Error bars represent standard errors. Different letters above bars indicate statistically significant differences at p ≤ 0.05; ns indicates no significant difference.

More Nitrogen Does not lead to high yield

Doubling the nitrogen rate to 180 lbs N/ac revealed something critical, more nitrogen doesn’t mean more yield. The yield pattern remained nearly identical to the 90 lbs N/ac rate. The 60 GDD timing produced the highest yield at 68 bu/ac, followed closely by 30 GDD at 67 bu/ac. The 90 GDD timing yielded 62 bu/ac, and the 120 GDD timing again crashed to 51 bu/ac. The only difference between the two rates was protein concentration (Figure 2). At 180 lbs N/ac, protein levels increased across all timings: 13% at preplant, 15% at both 30 and 60 GDD, 15-16% at 90 GDD, and 16% at 120 GDD. This confirms a fundamental principle: once farmers supply enough nitrogen to maximize yield potential, which occurred at 90 lbs N/ac in these trials, additional nitrogen only increases grain protein. It does not build more bushels. Unless farmers are receiving premium payments for high-protein wheat, that extra 90 lbs of nitrogen represents a cost with no yield return.

Figure 2: Grain protein response to nitrogen rate and application timing across three nitrogen rates: 45-45 lbs N/ac 90 lbs N/ac, and 180 lbs N/ac averaged across eight site-years in Oklahoma. Nitrogen was applied at five timings: 0, 30, 60, 90, and 120 GDDs. Error bars represent standard errors. Different letters above bars indicate statistically significant differences at p ≤ 0.05.

Should farmers split their nitrogen application?

Now that timing has been established as critical, the next question becomes: should farmers split their nitrogen applications, or is a single application sufficient? The conventional recommendation has been to split nitrogen apply part preplant to support early growth and tillering, then return with a second application later in the season to boost protein and finish the crop. But does the data support this practice? We compared three strategies at each timing: applying all nitrogen preplant, applying all nitrogen in-season at the target timing, or splitting nitrogen equally between preplant and in-season timing. The goal was to determine whether the extra trip across the field will deliver better results.

Our findings revealed that splitting provided no consistent advantage. At 30 GDD, all three strategies preplant, in-season, and split performed identically, producing 62-65 bu/ac with 12-13% protein (Figure 3 and 4). No statistical differences existed among them. At 60 GDD, similar pattern was held. Yields ranged from 61 to 66 bu/ac and protein stayed at 12-13% regardless of whether farmers applied all nitrogen preplant, all at 60 GDD, or split between the two. At 90 GDD, the single in-season application actually outperformed the split. While yields remained similar across all three methods (61-64 bu/ac), the in-season application delivered significantly higher protein at 13.7% compared to 12.4% for preplant and 12.5% for split applications. This suggests that concentrating nitrogen at 90 GDD, rather than diluting it across two applications, allows more efficient incorporation into grain protein. The only timing where splits appeared beneficial was 120 GDD, where the split application yielded 59 bu/ac compared to 51 bu/ac for the single late application. But this is not a win for splitting, it simply demonstrates that applying all nitrogen at 120 GDD is too late and putting half down earlier salvages some of the yield loss. Across all timings tested, splitting nitrogen into two applications offered no agronomic advantage over a single well-timed application, meaning farmers are making an extra pass for no gain in yield or protein.

Figure 3: Grain protein comparison among preplant, in-season, and split nitrogen applications averaged across eight site-years at (a) 30 GDD, (b) 60 GDD, (c) 90 GDD, and (d) 120 GDD timings. Error bars represent standard errors. Different letters above bars indicate statistically significant differences at p ≤ 0.05; ns indicates no significant difference; ns indicates no significant difference.
Figure 4: Grain yield comparison among preplant, in-season, and split nitrogen applications averaged across eight site-years at (a) 30 GDD, (b) 60 GDD, (c) 90 GDD, and (d) 120 GDD timings. Error bars represent standard errors. Different letters above bars indicate statistically significant differences at p ≤ 0.05; ns indicates no significant difference.

Practical Recommendations for Nitrogen Management

Based on three years of field data, farmers should target the 90 GDD timing (late tillering, Feekes 5-6) for their main nitrogen application to achieve the best balance between yield and protein. This window typically falls in late February to early March in Oklahoma, though farmers should monitor crop development rather than relying solely on the calendar apply when wheat shows multiple tillers, good green color, and vigorous growth. A rate of 90 lbs N/ac maximized yield in these trials; higher rates only increased protein without adding bushels, so farmers should only exceed this rate if receiving premium payments for high-protein wheat. Splitting nitrogen applications provided no advantage at any timing, meaning a single well-timed application at 90 GDD is sufficient for most Oklahoma wheat production systems. The exception would be sandy soils with high leaching potential, where splitting may reduce nitrogen loss. Farmers should avoid delaying applications until 120 GDD or later, as this timing consistently resulted in 15-25 bushel per acre yield losses even though protein increased. For farmers specifically targeting premium protein markets, a two-step strategy works best: apply 90 lbs N/ac at 90 GDD to establish yield potential and baseline protein, then follow with a foliar application of 20-30 lbs N/ac at flowering to push protein above 14% without sacrificing yield. Finally, weather conditions matter hot, dry forecasts increase volatilization risk and reduce uptake efficiency, so farmers should consider moving applications earlier if low humidity conditions are expected.

Split Application Caveat * Note from Arnall.

The caveat to the it only takes one pass, is high yielding >85+ bpa, environments. In these situation I still have not found any value for preplant nitrogen application. I have seen however a split spring application is valuable. Basically putting on 30-50 lbs at green-up, with the rest following at jointing (hollowstem). The method tends to reduce lodging in the high yielding environments.

This work was published in Front Plant Sci. 2025 Nov 6;16:1698494. doi: 10.3389/fpls.2025.1698494
Split nitrogen applications provide no benefit over a single well timed application in rainfed winter wheat

Another reason to N-Rich Strip.
Yet just one more data set showing the value of in-season nitrogen and why the N-Rich Strip concept works so well.

Questions or comments please feel free to reach out.
Brian Arnall b.arnall@okstate.edu
Acknowledgements: 
Oklahoma Wheat Commission and Oklahoma Fertilizer Checkoff for Funding.

What OK Cotton Growers Should Know about the Two-Spotted Cotton Leafhopper, aka Cotton Jassid

Ashleigh M. Faris, OSU Extension Cropping Systems Entomologist Department of Entomology and Plant Pathology Oklahoma State University

Jenny Dudak, OSU Extension Cotton Specialist, Department of Plant & Soil Sciences Oklahoma State University

Maxwell Smith, OSU IPM for Cotton Extension Specialist Department of Entomology and Plant Pathology, Oklahoma State University

Published 8.29.25

The two-spotted cotton leafhopper, also known as the cotton jassid (Amrasca biguttula), has not been detected in Oklahoma cotton production as of August 27, 2025. However, this insect pest has been confirmed to be causing significant injury in cotton fields that have high populations of the jassid throughout the southeastern United States (Figure 1). Although it is not known to currently be in Oklahoma cotton acres, our cotton growers and consultants are encouraged to keep an eye out for this pest and to report sightings of the insect or related damage to the OSU Cotton Extension team for confirmation.

Figure 1. Counties where the cotton jassid has been confirmed in the southeastern United States. Image courtesy of Dr. Isaac L. Esquivel (University of Florida), Dr. Phillip Roberts (University of Georgia), Dr. Scott Graham (Auburn University), and Dr. Jeremy Green (Clemson University).

Two-Spotted Cotton Leafhopper Identification & Injury

Cotton jassids are small, sap-sucking insects that are pale green insects with yellowish-green wings. They can be distinguished from most native North American species by the pair of black spots head and black spots on the tip of each wing (Figure 2). The immature nymph stages are even smaller than the adults; they are wingless but light green in color like the adults. (Figures 3 and 4).

Figure 2. Adult two-spotted cotton leafhopper, also known as cotton jassid. It can be identified by two black spots on the wings and head. Black spots on head can fade as the adult ages. Photo courtesy of Dr. Isaac L. Esquivel, University of Florida Extension.
Figure 3. Nymph two-spotted cotton leafhopper (cotton jassid). Photo courtesy of Dr. Isaac L. Esquivel, University of Florida Extension.
Figure 4. Cotton jassid nymphs on the underside of a leaf. Cotton jassids will progress through several instars before becoming adults. Photo courtesy of Dr. Isaac L. Esquivel, University of Florida Extension.

The cotton jassid feeds on the underside of leaves, causing hopperburn—a rapid yellowing, reddening, and browning that can quickly weaken plants (Figure 5). Initially, injury symptoms may look like nutrient deficiency with slight yellowing along the leaf tips and margins. Injury may also present as upward curling/cupping of the leaves. Once early symptoms are visible, leaves decline rapidly, turning red and brown. Because late-stage hopperburn can resemble a spider mite infestation, growers and consultants should scout for the pest causing injury prior to initiating control. Cotton jassid populations and hopperburn symptoms usually begin on field edges before moving into the cotton field.

Figure 5. Cotton plants displaying hopperburn. Note the yellowing, reddening, and browning of leaves. Photo courtesy of Dr. Isaac L. Esquivel, University of Florida Extension.

Suggested Threshold, Scouting, and Chemical Control Guidance

Current recommendations for the suggested threshold and chemical control options are based on insecticide trials conducted by University of Florida, University of Georgia, Clemson University, and the University of Auburn Extension Entomologists. The threshold at which treatment is recommended for the cotton jassid is 2 nymphs per leaf with injury present anywhere in the field. To scout, inspect the underside of the main stem leaf on the third, fourth, or fifth node from the top of the cotton plant. Sample a minimum of 25 leaves across plants and average counts across the number of leaves sampled.

In terms of management, multiple products seem to provide good efficacy. Bidrin (6 oz/a) has been consistent in multiple trials across Florida, Georgia, and South Carlina, but may be difficult if whiteflies are an issue. Centric (2 oz/a) and Transform (1.5 oz/a) seem to be consistent as well. One product that should not be used is Bifenthrin, which has proven not to be effective across multiple trials. Information on suggested chemical control options, their efficacy, and general IPM guidance will be forthcoming as more is learned about this pest in U.S. cotton systems.

If you detect the cotton jassid in Oklahoma cotton, please contact

IPM for Cotton Extension Specialist Maxwell Smith,

Cotton Extension Specialist Dr. Jenny Dudak,

Cropping Systems Extension Entomologist Dr. Ashleigh Faris.

PRE-EMERGENT RESIDUAL HERBICIDE ACTIVITY ON SOYBEANS, 2025

Liberty Galvin, Weed Science Specialist
Karina Beneton, Weed Science Graduate Student.

Objective

Determine the duration of residual weed control in soybean systems following the application of Preemergent (PRE) herbicides when applied alone and in tank-mix combination.

Why we are doing the research

PRE herbicides offer an effective means of suppressing early-season weed emergence, thereby minimizing competition during the critical early growth stage. However, evolving herbicide resistance and the need for longer-lasting weed suppression underscore the importance of evaluating multiple modes of action and their residual properties alone and tank-mixed.

Field application experimental design and methods

Field experiments were conducted in 2022, 2023, and 2024 growing seasons in Bixby, Lane, and Ft. Cobb FRSU Research Stations across Oklahoma. Each herbicide (listed in Table 1) was tested individually, in 2-way combinations, 3-way mixtures, and finally as 4-way combinations that included all active ingredients listed at the label rate.

Table 1. Preemergence herbicide active ingredients, trade name, mode of action, and rate.

Soybeans were planted at rates between 116,000 and 139,000 seeds/acre from late May to early June, depending on the year and location. The variety used belongs to the indeterminate mid- maturity group IV, with traits conferring tolerance to glyphosate (group 9 mode of action), glufosinate (group 10), and dicamba (group 4). Not all soybean varieties have metribuzin tolerance. Please read the herbicide label and consult your seed dealer for acquiring tolerant varieties. Row spacing was 76 cm at Bixby and Lane, and 91 cm at Fort Cobb. PRE treatments were applied immediately after planting at each experimental location.

POST applications consisted of a tank-mix of dicamba (XtendiMax VG® – 22 floz/acre), glyphosate (Roundup PowerMax 3®- 30 floz/acre), S-metolachlor (Dual II Magnum® – 16 floz/acre), and potassium carbonate (Sentris® – 18 floz/acre). Applications were made on different dates, mostly after the first 3 weeks following PRE treatments. These timings were based on visual weed control ratings, particularly for herbicides applied alone or in 2-way combinations, which showed less than 80% control at those early evaluation dates. The need for POST applications also depended on the species present at each site, with most fields being dominated by pigweed, as illustrated in the figure below.

Results

Tank-mixed PRE herbicide combinations generally provided superior residual control compared to a single mode of action application (Shown in Figure 1). Timely post-emergent (POST) herbicide applications helped sustain high levels of weed suppression, particularly as the effectiveness of residual PRE declined.

Figure 1. Weed control observed 29 days after PRE application (DAPRE) across different treatments. Plots 1 and 2 show high Palmer amaranth pressure, while plots 3 and 4 show a few escapes of Palmer and grass species.

Residual control of tank-mixed PRE

Some herbicides applied alone or in simple 2-way mixes, such as sulfentrazone + chloransulam- methyl and pyroxasulfone + chloransulam-methyl required POST applications within 20 to 29 days after PRE, indicating moderate residual control.

In contrast, 2-way combinations containing metribuzin, such as sulfentrazone + metribuzin and pyroxasulfone + metribuzin, extended control up to 50 days after PRE in some cases, highlighting metribuzin’s importance even in less complex formulations.

Furthermore, 3-way and 4-way combinations including metribuzin provided the longest-lasting control, delaying POST applications up to 51–55 days after PRE.

Injury of specific weeds

Palmer amaranth (Amaranthus palmeri) control in Bixby was consistently high (≥90%) at 2 weeks after PRE in 2022 and 2024 across all treatments. At 4 WAPRE, treatments containing metribuzin alone or in combination maintained strong control (90% or greater).

Texas millet (i.e., panicum; Urochloa texana) and large crabgrass (Digitaria sanguinalis) were effectively managed with most treatments delivering over 90% control early in the season and maintaining performance throughout. In 2024, control remained generally effective, though pyroxasulfone alone showed a temporary lack of control for Texas millet, and single applications declined in effectiveness against large crabgrass later in the season. These reductions were likely due to continuous emergence and the natural decline in residual herbicide activity due to weather. The most consistent late-season control for both species came from 3- and 4-way herbicide combinations.

Morningglory (Ipomoea purpurea) control reached full effectiveness (100%) only when POST herbicides were applied, across all years and locations. Their late emergence beyond the residual window of PRE herbicides reinforces the importance of sequential herbicide applications for season-long control.

Take home messages:

  • Incorporating PRE and POST herbicides slows the rate of herbicide resistance
  • Tank mixing with *different modes of action* ensures greater weed control by having activity on multiple metabolic pathways within the plant.
  • Tank mixing with PRE herbicides could reduce the number of POST applications required, and
  • Provides POST application flexibility due to residual of PRE application

For additional information, please contact Liberty Galvin at 405-334-7676 | LBGALVIN@OKSTATE.EDU or your Area Agronomist extension specialist.

Laboratory evaluation of Liquid Calcium

Liquid calcium products have been around for a long time. The vast majority of these products are either a calcium chloride or chelated calcium base which is now commonly found with the addition of a humic acid, microbial, or micronutrient. Many of these make promises such as “raises your soil pH with natural, regenerative, liquid calcium fertilizers that correct soil pH quickly, efficiently, and affordably!”. From a soil chemistry aspect the promise of adding 3 to 5 gallons of a Ca solution, which is approximately 10% Ca, will raise the soil pH is impossible on a mass balance approach. In this I mean that to increase the pH of an acid soil {soil pH is the ratio of hydrogen (H) and hydroxide (OH) in the soil, and having an acid soil means the concentration of H is greater than that of OH} requires a significant portion of the H+ that is in solution and on soil particle to be converted to OH, or removed from the system entirely.

The blog below walks through the full chemical process of liming a soil but in essence to reduce the H+ concentration we add a cation (positively charged ion) such as Ca or magnesium (Mg) which will kick the H+ of the soil particle and a oxygen (O) donator such as CO2 with ag lime or (OH)2 which is in hydrated lime. Each of these O’s will react with two H’s to make water. And with that the pH increases.

However regardless of the chemistry, there is always a lot of discussion around the use of liquid calcium Therefore we decided to dig into the question with both field and laboratory testing. This blog will walk through the lab portion.

This was a laboratory incubation study. The objective was to evaluation the impact of the liquid Ca product (LiqCa**) on the soil pH, buffer capacity, Ca content and CEC of two acidic soils. LiqCa was applied at three rates to 500 g of soil. The three rates were equivalent to 2, 4, and 6 gallon per acre applied on a 6” acre furrow slice of soil. One none treated check and two comparative products were also applied. HydrateLime (CaO) as applied at rate of Ca equivalent to the amount of Ca applied via LiqCa, which was approximately 1.19 pounds of Ca per acre. Also AgLime (CaCO3) was applied at rates equivalent to 1, 2, and 4 ton effective calcium carbonate equivalency (ECCE). The Ag lime used in the study had a measured ECCE of 92%. The two soils selected for both acidic but had differing soil textures and buffering capacities. The first LCB, had an initial soil pH (1:1 H2O) of 5.3 and a texture of silty clay loam and Perkins had a initial pH of 5.8 and is a sandy loam texture. Both soils had been previously collected, dried, ground, and homogenized. In total 10 treatments were tested across two soils with four replications per treatment and soil. 

Project protocol, which has been used to determined site specific liming and acidification rates, was to apply the treatments to 500 grams of soil. Then for a period of eight weeks this soil wetted and mixed to a point of 50% field capacity once a week then allowed to airdry and be mixed again. At the initiation and every two weeks after soil pH was recorded from each treatment. The expectation is that soil pH levels will change as the liming products are impacting the system and at some point, the pH reaches equilibrium and no longer changes. In this soil that point was week six however the trail was continued to week eight for confirmation. See Figures 1 and 2.

Figure 1. Soil pH measurement (1:1 H2O) collected from the LCB Soil at initiation, week 2, week 4, week 6, and week 8.
Figure 2. Soil pH measurement (1:1 H2O) collected from the Perkins Soil at initiation, week 2, week 4, week 6, and week 8.

ANOVA Main effect analysis showed that Soil was not a significant effect so therefore both soils were combined for further analysis. Figure 3 shows the final soil pH of the treatments with letters above bars representing significance between treatments. In this study all treatments were significantly greater than the check with exception of LiqCal 2 and CaO 6. Neither LiqCal or CaO treatments reached the pH level of Aglime, regardless of rate.

Figure 3. Final soil pH measurement (1:1 H2O) collected at week 8 for each treatment, average across both soils. Treatments with same letters are not significantly different at Alpha = 0.05.
Figure 4. Final Buffer pH collected at week 8 for each treatment, average across both soils. Treatments with same letters are not significantly different at Alpha = 0.05.
Figure 5. Final Ca (blue) and CEC (orange) in Cmol kg-1 collected at week 8 for each treatment, average across both soils. Treatments with same letters are not significantly different at Alpha = 0.05.

Summary

The incubation study showed that application of LiqCal at a rate of 4 and 6 gallons per acre did significantly increase the soil pH by 0.1 pH units and 6 gallons per acre increased the Buffer index above the check by 0.03 units. Showing the application of LiqCal did impact the soil. However the application of 1 ton of Ag lime resulted in significantly great increase in soil pH, 1.0 units by 8 weeks and a buffer index change of 0.2 units. The Aglime 1 was statistically greatly than all LiqCal treatments. Ag lime 2 and 4 were both statistically greater than Ag lime 1 with increasing N rate with increasing lime rate. Given the active ingredient listed in LiqCal is CaCl, this result is not unexpected. Ag lime changes pH by the function of CO3 reacting H+ in large quantities. In a unsupported effort a titration was performed on LiqCal, which show the solution was buffered against pH change. However it was estimated that a application of approximately 500 gallons per acre would be needed to sufficiently change the soil pH within a 0-6” zone of soil.

Results of the field study.
https://osunpk.com/2025/06/02/field-evaluation-of-lime-and-calcium-sources-impact-on-acidity/

Take Home

The application of a liquid calcium will add both calcium and chloride which are plant essential nutrients and can be deficient. In a soil or environment suffering from Cl deficiency specifically I would expect an agronomic response. However this study suggest there is no benefit to soil acidity or CEC with the application rates utilized (2, 4, and 6 gallon per acre).

** LiqCal The product evaluated was derived from calcium chloride. It should be noted that since the completion of the study this specific product used has changed its formulation to a calcium chelate. This change however would not be expected to change the results as the experiment did include a equivalent calcium rate of calcium oxide.

Other articles of Interest

https://extension.psu.edu/beware-of-liquid-calcium-products

https://foragefax.tamu.edu/liquid-calcium-a-substitute-for-what/

Any questions or comments feel free to contact me. b.arnall@okstate.edu

Field evaluation of lime and calcium sources impact on Acidity.

At the same time we initiated a lab study looking at the application of LiqCal https://osunpk.com/?p=2096 , we also initiated a field trial to look at the multi-year application of LiqCal, Pelletized Lime and Ag-Lime.

A field study was implemented on a bermudagrass hay meadow near Stillwater in the summer of 2019. The study looked to evaluate the impact of multiple liming / calcium sources impact on forage yield and soil properties. This report will focus on the impact of treatments on soil properties while a later report will discuss the forage results.
Table 1. has the management of the six treatments we evaluated, all plots had 30 gallons of 28-0-0 streamed on each spring in May. Treatment 1 was the un-treated check. Treatment 2, was meant to be a 2 ton ECCE (Effective Calcium Carbonate Equivalency) Ag Lime application when we first implemented the plots in 2019, but we could not source any in time so we applied 2.0 ton ECCE hydrated lime (CaO) the next spring. The spring 2023 soil samples showed the pH to have fallen below 5.8 so and Ag lime was sourced from a local quarry and 1.0 ton ECCE was applied May 2024. Treatment 3, was meant to complement Treatment 2 as an additional lime source of hydrated lime, it was applied June 2019. My project has used hydrated lime as a source for many years as it is fast acting and works great for research. Treatment 4 had 100 lbs. of pelletized lime applied each spring. The 100 lbs. rate was based upon recommendation from a local group that sells Pell lime. Treatments 5 and 6 were two liquid calcium products *Liq Cal * and **Lig Cal+ from the same company. The difference based upon information shared by the company was the addition of humic acid in the Liq Cal+ product. Both LiqCal and LiqCal+ where applied at a rate of 3 gallons per acre per year, with 17 gallons per acre of water as a carrier. Table 1, also shows total application over the six years of the study.

Table 1. Treatments of the field study. Each treatment was replicated 4 times.

After six years of applications and harvest it was decided to terminate the study. The forage results were intriguing however little differences where seen in total harvest over the six years, highlighting a scenario I have encountered in the past on older stands of bermuda. That data will be shared in a separate blog.
The soils data however showed exceptionally consistent results.

In February of 2025 soil samples were collected from each plot at depths of 0-3 inch’s and 0-6 inches (Table 2.). It was our interest to see if the soil was being impacted below the zone we would expect lime and calcium to move without tillage, which if 0-3″. Figure 1. below shows the soil pH of the treatments at each depth. In the surface (blue) the Ag Lime and Hydrated lime treatments both significantly increased from 4.78 to 6.13 and 5.7 respectively. While the Pel lime, LiqCal and LiqCal+ had statistically similar pH’s as the check at 4.8, 4.65, and 4.65. It is important to note that the Ag Lime applied in May of 2024 resulted in a significant increase in pH from the 2019 application of Treatment 3. The Spring of 2024 soil samples showed that the two treatments ( 2 and 3 ) were equivalent. So within one year of application the Ag lime significantly raised soil pH.

As expected the impact on the 3-6″ soil pH was less than the surface. However, the Ag Lime and Hydrated lime treatments significantly increased the pH by approximately 0.50 pH units. This is important data as the majority of the literature suggestion limited impact of lime on the soil below the 3″ depth.

Figure 1. Soil pH (1:1 extraction) results of by plot soil sample results collected from 0-3″ and 3-6″ soil depths. Fifteen soil cores collected from each plot. Soils collected February 2025. Treatments with same letters are not significantly different at Alpha = 0.05

The buffer pH of a soil is used to determine the amount of lime needed to change the soils pH. In Figure 2. while numeric differences can be seen, no treatment statistically impacted the buffer pH at any soil depth.

Figure 2. Soil Buffer pH (Sikora extraction) results of by plot soil sample results collected from 0-3″ and 3-6″ soil depths. Fifteen soil cores collected from each plot. Soils collected February 2025. Treatments with same letters are not significantly different at Alpha = 0.05

The soil calcium level was also measured. As with 0-3″ pH and Buffer pH the Ag Lime and Hydrated lime had the greatest change from the check. These treatments were not statistically greater than the Pell Lime but where higher than the LiqCal and LiqCal+.

Figure 3. Soil calcium concentrations (lbs ac-1) results of by plot soil sample results collected from 0-3″ and 3-6″ soil depths. Fifteen soil cores collected from each plot. Soils collected February 2025. Treatments with same letters are not significantly different at Alpha = 0.05

Table 2. Soil test results from the February soil sampling. Depth 1 is 0-3″ and Depth 2 is 3-6″.
Each value is the average of four replicates.

Take Homes
In terms of changing the soils pH or calcium concentration, as explained in the blog https://osunpk.com/2023/01/24/mechanics-of-soil-fertility-the-hows-and-whys-of-the-things/, it takes a significant addition of cations and oxygens to have an impact. This data shows that after six years of continued application of pelletized lime and two liquid calcium products the soil pH did not change. While the application of 2 ton ECCE hydrate lime did.
Also within one year of application Ag lime the soil pH significantly increased.

* LiqCal The product evaluated was derived from calcium chloride. It should be noted that since the completion of the study this specific product used has changed its formulation to a calcium chelate. This change however would not be expected to change the results as the experiment did include a equivalent calcium rate of calcium oxide.

** LiqCal+ The product evaluated was derived from calcium chloride. It should be noted that since the completion of the study this specific product used has changed its formulation. The base was changed from calcium chloride to a calcium chelate. Neither existing label showed Humic Acid as a additive, however the new label has a a list of nutrients at or below 0.02% (Mg, Zn, S, Mn, Cu, B, Fe) and Na at .032% and is advertised as having microbial enhancements.

Any questions or comments feel free to contact me. b.arnall@okstate.edu

Sorghum Nitrogen Timing

Contributors:
Josh Lofton, Cropping Systems Specialist
Brian Arnall, Precision Nutrient Specialist

This blog will bring in a three recent sorghum projects which will tie directly into past work highlighted the blogs https://osunpk.com/2022/04/07/can-grain-sorghum-wait-on-nitrogen-one-more-year-of-data/ and https://osunpk.com/2022/04/08/in-season-n-application-methods-for-sorghum/

Sorghum N management can be challenging.  This is especially true as growers evaluate the input cost and associated return on investment expected for every input.  Recent work at Oklahoma State University has highlighted that N applications in grain sorghum can be delayed by up to 30 days following emergence without significant yield declines.  While this information is highly valuable, trials can only be run on certain environmental conditions. Changes in these conditions could alter the results enough to impact the effect delay N could have on the crop.  Therefore, evaluating the physiological and phenotypic response of these delayed applications, especially with varied other agronomic management would be warranted.

One of the biggest agronomic management sorghum growers face yearly is planting rate.  Growers typically increase the seeding rate in systems where specific resources, especially water, will not limit yield.  At the same time, dryland growers across Oklahoma often decrease seeding rates by a large margin if adverse conditions are expected.  If seeding rates are lowered in these conditions and resources are plentiful, sorghum often will develop tillers to overcome lower populations.  However, if N is delayed, there is a potential that not enough resources will be available to develop these tillers, which could decrease yields. 

A recent set of trials, summarized below, shows that as N is delayed, the number of tillers significantly decreases over time.  Furthermore, the plant cannot overcompensate for the lower number of productive heads with significantly greater head size or grain weight. 

This information shows that delaying sorghum N applications can still be a viable strategy as growers evaluate their crop’s potential and possible returns.  However, delayed N applications will often result in a lower number of tillers without compensating with increased primary head size or grain weight.

Figure 1. Number of tillers for different fertilization timings of sorghum.  Timing was at planting as well as 21 and 42 days after emergence.
Figure 2. Impact of fertilizer timing on sorghum head width. This was measured from the middle of the head at harvest. Timing was at planting as well as 21 and 42 days after emergence.
Figure 3. Sorghum 100-seed weight (g) impacted by fertilizer timing. Timing was at planting as well as 21 and 42 days after emergence.

This date on yield components is really interesting when you then consider the grain yield data. The study, which is where the above yield component data came from, was looking at population by N timing. The Cropping Systems team planted 60K seeds per acre and hand thinned the stands down to 28 K (low) and 36K (high). The N was applied at planting, 21 days after emergence, and 42 days after emergence. The rate of N applied was 75 lbs N ac. It should be noted both locations were responsive to N fertilizer.

Grain yield yield from Bixby
Grain yield from Chickasha

In the data you can without question see how the delayed N management is not a tool for any of members of the Low Pop Mafia. However those at what is closer to mid 30K+ there is no yield penalty and maybe a yield boost with delayed N. The extra yield is coming from the slightly heavier berries and getting more berries per head. Which is similar to what we are seeing in winter wheat. Delaying N in wheat is resulting in fewer tillers at harvest, but more berries per head with slightly heavier berries.

Now we can throw even more data into the pot from the Precision Nutrient Management Teams 2024 trials. The first trial below is a rate, time and source project where the primary source was urea applied in front of the planter for pre in range of rates from 0-180 in 30 lbs increments. Also applied pre was 90 lbs N as Super U. Then at 30 days after planted we applied 90 lbs N as urea, SuperU, UAN, and UAN + Anvol.
Pre-plant urea topped out at 150 lbs of Pre-plant (57 bushel), but it was statistically equal to 90 lbs N 51 bushel. The use of SuperU pre did not statistically increase yield but hit 56 bushel. The in-season shots of 90 lbs of UAN, statistically outperformed 90 pre and hit our highest yeilds of 63 and 62 bushel per acre. The dry sources in-season either equaled their in preplant counter parts.

Perkins sorghum N study, which evaluated rate, timing and source. Pre-plant was applied at planting, SU stands for SuperU (Koch), SD- Sidedness applied 30 days after planting, UAN and UAN + (which was UAN + Anvol) was applied via drop nozzles on 30″ centers.

The Burn Study at Perkins, showed that the N could be applied in-season through a range of methods, and still result good yields. In this study 90 lbs of N was used and applied in a range of methods. The treatments for this study was applied on a different day than the N source. Which you can see in this case the dry untreated urea did quite well when when applied over the top of sorghum. In this case we are able to get a rain in just two days. So we did get good tissue burn but quick incorporation with limited volatilization.

Perkins Burn study in which all treatments received 90 lbs of N applied approximately 30 days after planting.

Take Home:
Unless working in low population scenarios. The data show that we should not be getting into any rush with sorghum and can wait until we know we have a good stand. We also have several options in terms of nitrogen sources and method of application.

Any questions or comments feel free to contact Dr. Lofton or myself
josh.lofton@okstate.edu
b.arnall@okstate.edu

Funding Provided by The Oklahoma Fertilizer Checkoff, The Oklahoma Sorghum Commission, and the National Sorghum Growers.

Boosting Wheat Grain Protein: Smart Spray Strategies for Better Grain Quality

Brian Arnall, Precision Nutrient Management Specialist
Samson Abiola, PNM Ph.D. Student.

Wheat Protein and Technology challenge
For wheat growers, achieving both high yields and good protein content is a constant challenge. Wheat contributes about 20% of the world’s calories, making it a vital crop for global nutrition. Every season, we face the question of how to boost grain protein concentration (GPC) without sacrificing the yield.

Traditional approaches often involve applying more nitrogen (N) early in the season. While this can help, it is often wasteful, environmentally problematic, and does not always translate to higher protein levels at harvest. The effectiveness of N applications depends not just on timing but also on the spray technology used, including the N source, nozzle type, and droplet size. While protein premiums are never guaranteed, we wanted to develop recommendations prior to the need.

The Research Approach: Timing and Technology

Our research team conducted a comprehensive three-year study (2019-2022) across three Oklahoma locations (Perkins, Lake Carl Blackwell, and Chickasha) to investigate how different combinations of N sources, nozzle types, and droplet sizes affect protein when applied during flowering. We considered two N sources (urea-ammonium nitrate (UAN) and aqueous urea [Aq. Urea]). We also evaluated three nozzle types: Standard flat fan (FF) nozzles with a traditional 110° spray angle, 3D nozzles with three-dimensional spray patterns that enhance canopy penetration, Twin (TW) nozzles with dual forward and rear facing sprays (30° forward and backward)

Finally, we tested both fine droplets (below 141 microns) and coarse droplets (≥141 microns). All applications were made at flowering i.e., when you start seeing yellow anthers sticking out of the wheat heads. Both UAN and Aq. urea were applied at a 20 gpa application rate with a 1:1 dilution with water delivering approximately 30 lbs. of N per acre.

What We Found: More Protein Without Hurting Yield

The big news? Spraying N at flowering boosted wheat protein by 12% without sacrificing yield. This held true across fields yielding anywhere from 30 to 86 bushels per acre. Why doesn’t it hurt yield? By flowering time, your wheat has already “decided” how many heads and kernels it will produce. The N you spray at this stage goes straight to building protein in those existing kernels.

One important caution: Mother Nature still calls the shots, so keep an eye on the forecast before planning your application. If the weather is hot and dry, this is not a good idea. First, those environments typically result in higher protein anyways. But low humidity will significantly increase the likelihood of burn.

Lake Carl Blackwell Findings: UAN Takes the Lead

At our Lake Carl Blackwell site, we saw our highest protein levels reaching up to 16.3% in some plots. In 2020-21, UAN clearly beat Aq. urea (14.7% vs. 14.0% protein). Both were much better than not applying any N at flowering (13.1%) (Figure 1A). Also, the 3D nozzle gave us the highest protein (14.7%), outperforming the control but performing similarly to FF (14.0%) and TW nozzles (14.2% (Figure 1B). The next year (2021-22) showed us something interesting, the combination of N source and droplet size really matters. UAN with fine droplets hit 14.6% protein, similar to UAN with coarse droplets (14.4%) and Aq. urea with coarse droplets (14.3%), but Aq. urea with fine droplets fell behind at just 13.8% (Figure 1C).

Figure 1. Main effect of foliar N treatments on GPC (%) at Lake Carl Blackwell in 2020–21: (A) nitrogen source effect; (B) nozzle type effect; and 2021–22: (C) N source and droplet interactions effect. Error bars represent standard errors of means. Different letters above bars indicate statistically significant differences at p ≤ 0.05.

Chickasha Results: Matching Your N to the Right Droplet Size

At Chickasha, protein ranged from 10.1% to 13.8% across the two years we studied. In 2021-22, UAN beat Aq. urea (12.7% vs. 12.2%), and both beat the control (11.8%) (Figure 2A). Also, the 3D nozzle (12.8%) outperformed both FF and TW nozzles (both 12.2%) (Figure 2B).

In 2020-21, we found that the combination of N source, nozzle type, and droplet size all worked together to affect protein. The winning combination was UAN with 3D nozzle and fine droplets (13.23% protein), which performed similarly to Aq. urea with TW nozzle and coarse droplets (13.18%) (Figure 2C). The least performer was Aq. urea with TW nozzles and fine droplets (12.20%) among the treatments. This shows how weather and growing conditions can change which factors matter most from year to year

Figure 2. Effect of foliar N treatments on GPC (%) at Chickasha: (A) nitrogen source effect in 2020-21; (B) nozzle type effect in 2020-21; and (C) nitrogen source × droplet type interaction effect in 2021-22. Error bars represent standard errors of means. Different letters above bars indicate statistically significant differences at p ≤ 0.05

Perkins Results: Getting Every Detail Right

At our Perkins site, we saw protein levels ranging from 10% to 13.1%. Here, the combination of all three factors (N source, nozzle type, and droplet size) made a huge difference. The best setup was UAN with 3D nozzle and coarse droplets (12.2% protein). The worst was Aq. urea with TW nozzle and fine droplets (10.5%) (Figure 3). That’s a 15% difference that could mean the difference between premium and feed-grade wheat!

UAN consistently outperformed Aq. Urea across all setups. For example, UAN with 3D nozzle and coarse droplets produced 10% higher protein than the same setup with Aq. Urea.

Figure 3. Three-way interaction effects on GPC (%) at Perkins in 2020–21 (A) and at Perkins 2020–21 (B). Error bars represent standard errors of means. Different letters above bars indicate statistically significant differences at p < 0.05.

Equipment and Application Recommendations

Over the three years UAN consistently outperformed perform Aq. urea, showing there is no need for a special formulation and that commercially available UAN is all we really need as a source. While no nozzle type significantly stood out across all sites the 3-D nozzle did show up a couple times as being statistically better. So the important message would be that while the high tech nozzles could provide some value the traditional flat fan performed quite well. While some differences were seen in droplet size, the lack of consistency leads us to say focus on good coverage with limited drift.

Take-Home Messages

  1. Foliar N at flowering boosted wheat protein by 12% without affecting yield multiple growing seasons and locations. This increase was from 0.5 to nearly 2.0 % protein.
  2. Nitrogen source matters – UAN consistently outperformed Aq. Urea.
  3. Your spray technology mattered but not lot – and 3D nozzles generally gave the best results. The good ole flat fans nozzles still did quite will.
  4. Match droplet size to your setup – generally fine for UAN and coarse for Aq. Urea.
  5. This targeted approach enhances grain quality without sacrificing yield, potentially improving grain prices and profitability while using N more efficiently.
  6. Mother Nature still calls the shots, so keep an eye on the forecast before planning your application. If the weather is hot and dry, this is not a good idea. First, those environments typically result in higher protein anyways. But low humidity will significantly increase the likelihood of burn.

This blog was written based upon the data published in the manuscript “Optimizing Spray Technology and Nitrogen Sources for Wheat Grain Protein Enhancement” which is available for free reading and downloading at https://www.mdpi.com/2077-0472/15/8/812

Any questions or comments feel free to contact me. b.arnall@okstate.edu

Nitrogen and Sulfur in Wheat

Brian Arnall, Precision Nutrient Management Specialist
Samson Abiola, PNM Ph.D. Student.

Nitrogen timing in wheat production is not a new topic on this blog, in-fact its the majority. But not often do we dive into the application of sulfur. And as it is top-dressing season I thought it would be a great opportunity to look at summary of a project I have been running since the fall of 2017 which the team has call the Protein Progression Study. The objective was to evaluate the impact of N and S application timings on winter wheat grain yield and protein. With a goal of looking at the ratio of the N split along with the addition of S and late season N and S, in such a way that we could determine BMP for maximizing grain yield and protein.

Treatment structure for the Protein Progression Project. 100% N value was based on local yield goal and residual N, however it was commonly 120 lbs N per acre. Top-dress N applied as Urea and S as AMS at 10 lbs S per acre. Late foliar N was applied as a 50/50 UAN/water blend at 20 gpa. Late S was ATS blended with the UAN/water mix to apply 10 lbs S per acre. Anthesis is the flowering stage.

My work in the past has shown two things consistently, that spring N is better on the average and S responses have been limited to deep sandy soils in wet years. Way back when (2013) on farm response strips showed high residual N at depth and no response to S. https://osunpk.com/2013/06/28/response-to-npks-strips-across-oklahoma/. But there has been a lot of grain grown since that time expectations are that we should/are seeing an increase in S response. In fact Kansas State is seeing more S response, especially in the well drained soils in east half of the state.
Some KSU Sulfur works.
https://www.ksre.k-state.edu/news/stories/2022/04/video-sulfur-deficiency-in-wheat.html
https://eupdate.agronomy.ksu.edu/article/sulfur-deficiency-in-wheat-364-1
Click to access sulphur-in-kansas-plant-soil-and-fertilizer-considerations_MF2264.pdf

So the Protein Progression Project was established in 2017 and where ever we had space we would drop in the study. So in the end across six seasons we had 13 trials spread over five locations. Site-years varied by location: Chickasha (2018-2022), Lake Carl Blackwell (2018-2023), Ballagh (2020), Perkins (2021), and Caldwell (2021).

Locations of the Protein Progression Project which was conducted in harvest years of 2018-2023. From north to south locations were Caldwell, Ballagh, LCB, Perkins, and Chickasha.

First lets just dive into the the N application were we looked at 100% pre vs 50-50 split and 25-75 split (Table 2.) Based upon the wealth of previous work https://osunpk.com/2022/08/26/impact-of-nitrogen-timing-2021-22-version/, its not much of a surprise that split application out preformed preplant and that having the majority applied in-season tended to better grain yields and protein values.

Grain yield and protein content of 100% pre vs 50-50 split and 25-75 split treatments by location for the Protein Progression study. Values with the same letters are not statistically different, and if there are no letter no significance was found.

This next table is were things get to be un-expected. While the data below is presented by location, we did run each site year by itself. In no one site year did S statistically, or numerically increase yield. As you can see in Table 2 below, the only statistical response was a negative yield response to S. And you can not ignore the trend that numerically, adding S had consistently lower yields. Even more surprising was the same trend was seen in Protein.

Grain yield and protein content of 25-75 and 25-75 + S treatments by location for the Protein Progression study. Values with the same letters are not statistically different, and if there are no letter no significance was found.

One aspect of Protein Progression trials were that while 0-6″ soil test S tended to be low. We would often find pretty high levels of S when we sampled deeper, especially when there was a clay increase with depth. Sulfur tends to be held by the clay in our subsoil. We are also looking at better understanding the relationship between N and S. In fact a review article published in 2010 discussed that the N and S ratio can negative influence crop production when either one of the elements becomes un-balanced. For example we are seeing more often in corn that when N is over applied we can experience yield loss, unless we apply S. Meaning at 200 lbs of N we make 275 BPA, at 300 N lbs we make 250, but 300 N plus 20 S we can make 275 again. Part of the rationale is that excessive N limits S mineralization. On the flip side if S is applied while N is deficient and yield decrease could be experienced. Maybe that is what we are seeing in this date. Either way, this data is why the Precision Nutrient Management program is spending a fair amount of efforts in understanding the N x S relationship in wheat (which we are looking at milling quality also) and corn.

A quick dive into increasing protein with late N applications. At three of the five location GPC was significantly increased with Late N. In most cases the anthesis (flowering) application was the highest with exception of Caldwell. We will have another blog coming out in a month that digs into anthesis applied N at a much deeper level, looking at source, nozzle and droplet sizes.

Grain protein content of 25-75, 25-75 + Anthesis N and 25-75 + Flag Leaf N treatments by location for the Protein Progression study. Values with the same letters are not statistically different, and if there are no letter no significance was found.

Looking at this study in a vacuum we can say that it probably best to split apply your N and that in central and northern Ok the addition of S in rainfed wheat doesn’t offer great ROI. If I look at the whole picture of all my work and experience I would offer this. For grain only wheat, the majority if not all N should be applied in-season sometime between green up and two weeks after hollow stem. I have had positive yield responses to S applied top-dress, but it has always been deep sandy soils and wet seasons. I have not have much is any response to S in heavier soil, especially if there is a clay increase in the two feet of profile. So my general S recommendation is 10 lbs in sandy soils and if you show low soil test S in heavier ground and you are trying to push grain yields, then you could consider the addition of S as a potential insurance. That said, I haven’t seen much proof of it.

Take Homes
* Split application of nitrogen resulted in higher grain yields and protein concentrations when compared to 100% preplant.
* Putting on 75% of the total N in-season tended to result in higher grain yields and protein concentrations when compared to 50-50 split.
* Adding 10 lbs of S topdress did not result in any increase in grain yield or protein.

A big Thanks to the collaborators providing on-farm locations for this project. Ballagh Family Farms, Turek Family Farms and Tyler Knight.

Citation. Jamal, A.,*, Y. Moon, M. Abdin. 2010 Review article. Sulphur -a general overview and interaction with nitrogen. AJCS 4(7):523-529 (2010). ISSN:1835-2707.

Any questions or comments feel free to contact me. b.arnall@okstate.edu

A comparison of four nitrogen sources in No-till Wheat.

Jolee Derrick, Precision Nutrient Management Masters Student.
Brian Arnall, Precision Nutrient Management Specialist.

Nitrogen (N) fertilizer’s ability to be utilized by a production system is reliant upon the surrounding environment. The state of Oklahoma’s diverse climate presents unique challenges for producers aiming to apply fertilizers effectively and mitigate the adverse effects of unfavorable conditions on nitrogen fertilizers. To lessen the effect that unfavorable environments can have on N fertilizers, chemical additions have been introduced to base fertilizers to give the best possible chance at an impact. With that in mind, a study was conducted to investigate the impact of N sources and application timings on winter wheat grain yield and protein, aiming to identify both the agronomic effects of these sources and how variations in their timing may influence the crop. Included below is a figure of where and when the trials were conducted.

Figure 1. Map of Oklahoma with the Locations of Trials Highlighted. Color indicates years where each trial was active. Red denotes a 20-21 growing season. Purple demonstrates active trials from 20-24. Blue indicates 22-23 growing season. Yellow expresses active trials from 20-23.

In each of the trials, four N sources (Urea, SuperU, UAN, and UAN + Anvol) were analyzed across a range of timings. The sources were categorized on two criteria: application type, distinguishing between dry and liquid sources, and the presence of additives versus non-additives. The two N sources were Urea and UAN. The other products in this study were SuperU and Anvol. SuperU is a N product that has Dicyandiamide (DCD) and N- (n-butyl) thiophosphoric triamide (NBPT) incorporated into a Urea base. Anvol is an additive product which contains NBPT and Duromide and can be incorporated with dry or liquid N sources.

For additional clarification, N- (n-butyl) thiophosphoric triamide is a urease inhibitor which prevents the conversion of urea to ammonia. Duromide is a molecule which is intended to slow the breakdown of NBPT. DCD is a nitrification inhibitor that slows the conversion of ammonium to nitrate.

Urea is a stable molecule which in the presence of moisture is quickly converted to stable ammonium (NH4), however it can be converted to ammonia gas (NH3) by the enzyme urease beforehand. Additionally, when urea is left on the soil surface and not incorporated via tillage or ½ inch of a precipitation event, the NH4 that was created from urea can be converted back to NH3 and gasses off. So, the use of urease inhibitors is implemented to allow more time for incorporation of the urea into the soil.

Ammonium in the soil is quickly converted to nitrate (NO3) by soil microbes when soil temperature is above 50F°. When N is in the NO3 form it is more susceptible to loss through leaching or denitrification. Therefore, nitrification inhibitors are applied to prevent the conversion of NH4 to NO3.

All treatments were applied at the same rate of 60 lbs of N ac-1, which is well below yield goal rate. A lower N rate was chosen to allow the efficacy of the products to express themselves more clearly, rather than a higher rate that may limit the ability to determine differences between product and rate applied. Furthermore, dry N sources were broadcasted by hand across the plots while liquid sources were applied by backpacking utilizing a handheld boom with streamer nozzles. Application timing dates were analyzed by identifying the growing degree days (GDD) associated with each timing which were correlated with the Feekes physiological growth chart displayed in Figure 3. Over the span of the study, N has been applied over six stages of growth. The range of application dates stems from the fact that it is difficult to get across all the ground exactly when you need to.

Figure 2. Growing Degree Days (GDD) Correlation with Growth Stages. Growth stages that were analyzed in this study are highlighted by stars.
Figure 3. Graph depicting yield and protein of N sources across all SYs and application timings. Analysis between sources was completed with a Tukey pairwise test set at α = 0.10. Uppercase letters depict statistical difference at a p < 0.10 level for grain yield. Lowercase letters depict a statistical difference at p < 0.10 for grain protein percentages.

Over four years this study was replicated 11 times. Of those 11 site years, three did not show a response to N, so they were removed from further analysis. The graph above shows the average yield of each respective source (across all locations and timings). The data shows there is a statistical difference between SuperU and Urea vs. UAN, but no statistical difference between UAN treated Anvol and any other source. The data indicates that on average, a dry source resulted in a higher yield than when a liquid source was applied. This makes sense considering that in many cases, wheat was planted in heavy residue during cropping seasons that experienced prolonged drought conditions. Therefore, it is thought that a liquid source can get tied up in the residue. This was first reported in a previous blog posting, Its dry and nitrogen cost a lot, what now?, and years later, the same trends in new data indicate the same conclusion.

Figure 4. Image showing surface crop residue at the Miami location

If we look at all timings and site years averaging together there is no statistical difference between a raw N source and its treated counterpart. This result is not surprising as we would expect that not all environments were conducive to loss pathways that the products prevented. Basically, we would not expect a return on investment in every single site year, and therefore you do not see broad sweeping recommendations. There was a 2-bushel difference between UAN and UAN Anvol.  As this was a numerical difference, not a statistical one, I would say that while the yield advantage was not substantial there may be economic environments that would suggest general use. 

Figure 5. Average grain yield and protein percentage for each source based upon each application timing across all SYs. Excluding Site Years 4, 9, and 10. Statistical differences were assessed through Tukey HSD test where differing letters are statistically different (α=0.1) and demonstrate differences in grain yields. Statistical differences are separated by application timings correlated with approximate month of application. The amount of SYs represented in each application timings are denoted below the months.

While the evaluation of the four sources across all timings and locations showed some interesting results, this work was performed to see if there was a timing of application which would have a higher probability of a safened N returning better yields.  As you look at the chart above it is good to remember the traditional trend for precipitation in Oklahoma, where we tend to start going dry in November and stay dry through mid-January. Rain fall probability and frequency starts to increase around mid-February, but moisture isn’t consistent until March. This project was performed during some of the dryest winters we have seen in Oklahoma. Also, just a note, since the graph above combines all the sites that have differing application dates the absolute yields are a bit deceiving. For example, the Nov and Feb timings include the locations with our highest yields 80+ bpa per acre, while January and February include our lowest.  So, the way this data is represented we should not draw conclusions about best time for N app. For that go read the blogs Impact Nitrogen timing 2021-2022 Version  and Is there still time for Nitrogen??

Figure 6a and b. A: The mesonet rainfall totals for Oct -Dec for the Lake Carl Blackwell research station for 2020-2023 A: The mesonet rainfall totals for Jan – April  for the Lake Carl Blackwell research station for 2021-2024. The black line on both graphs is the 10 year average.

Now about the source by time. While it’s not always statistical you can see that the dry sources tend to outperform the liquid sources at most timings. Also, while there is never a statistical difference in the raw product and safened, there are trends. SuperU tended to have higher yields than urea when applied in Nov and Dec. It could be hypothesized that the addition of a nitrification inhibitor may have added value, however the UAN + Anvol in November also showed a positive response that would point to the value being derived from urease inhibition. As we move into the period of more consistent rainfall the differences between products start declining, which also makes sense.

The following figures illustrate rainfall events following N application, with the application dates indicated by arrows. Figure 7 corresponds to our trial conducted in 2020-2021, which revealed no statistical differences among the N sources for any timing. However you can see that for the first timing (orange bars) which received 0.7″ of rain two days after application that the yields are uniform than the grey bars with both safened products are numerically greater than the raw product, just makes since as a 0.1″ precipitation event happened 6 days application application and it wasn’t until day 9 that a good incorporating rainfall occurred.

Figure 7. Graph showing rainfall patterns for the Lake Carl Blackwell 2020-2021 season. The arrow indicates the date of application for both 1st and 2nd application timings. Precipitation data was retrieved from the Oklahoma Mesonet. Accumulation of rain is represented by inches. Graph in the upper corner showcases grain yield averages for each source per timing application timing.

Figure 8 has data the same location one year later, during which we observed statistically significant differences among the dry and liquid N sources. The environmental conditions during 2022 were drier, impacting the incorporation of N applications. The lack incorporating rainfall likely led to tie-up of the UAN on/in the residue, limiting access to plant available N.

Figure 8. Graph showing rainfall patterns for the Lake Carl Blackwell 2021-2022 season . Where arrow indicates the date of application for both 1st and 2nd application timings. Meteorological data was retrieved from the Oklahoma Mesonet. Accumulation of rain is represented by inches.  Graph in the upper corner showcases grain yield averages for each source per timing application timing.

It is essential to highlight the environmental conditions encountered throughout this project. From 2020 to 2023, moderate to extreme drought conditions were prevalent. During this period, the influence of a La Niña led to reduced moisture availability. For the first time in an extended period, the 2023-2024 wheat year began under a strong El Niño, which typically results in increased moisture accumulation compared to its La Niña counterpart. Currently, there are indications that a return to a La Niña system may occur by the end of the year, raising the expectation of a potential reversion to drought conditions. Consequently, this research may provide producers with options to consider regarding sources of N application in their production systems.

We plan to update this blog with a deeper analysis of the results seen at each location as soon as possible. But for now, we wanted to share the early look.

At this point the reason for the liquid yield gap is speculation. It could be increased loss via ammonia volatilization or it could be immobilization of the N by microbes. The next step of this process is to understand 1) is the UAN tied up in the residue via immobilization via microbes or is it lost to volatilization. 2) If tied up, what is the time frame between application and immobilization.

Take Home:

  • It was observed that during low moisture conditions, dry N sources had significantly better results than liquid counterparts in no-till winter wheat production.
  • On average, additive products had no significant impact on grain yield versus base fertilizers, however, when evaluated by location, differences could be found. Responses usually correlated with post-application weather conditions.
  • When adequate precipitation was received shortly after application, N sources did not show differences.

Any questions or comments feel free to contact me. b.arnall@okstate.edu

In-Furrow Placement of Urea Products with Wheat Seed

Its that time of year I always get the question of “How much urea can I put in the furrow?”. My answer is always two fold first, I wouldn’t recommend it, its a risky venture. Even though I know some do it. Second, my research shows very little is any value from N in furrow. I like P but N just doesn’t show me any return. So for me the process is high risk, with little or no potential for return. But with blog I turn to our purple friend up north to share what their research has sown.

Brian

Guest Authors Kansas State University
Lucas Haag, Agronomist-in-Charge, Southwest Research-Extension Center, Tribune lhaag@ksu.edu
Alan Schlegel, retired
Dorivar Ruiz Diaz, Nutrient Management Specialist ruizdiaz@ksu.edu

To save time and cost, some wheat producers may be thinking about adding a little extra nitrogen (N) as urea or UAN to their phosphorus fertilizer through the drill with the seed. This would either be in addition to, or instead of, any preplant N applications.

While a minimum preplant N application of 20 to 40 lbs N per acre is often desirable, especially in no­ till production systems, there are risk involved when placing urea containing fertilizers in direct seed contact. Traditionally, we have suggested that no urea or UAN solution be placed in contact with the seed. With the continued adoption of air-seeders a common question we receive from producers is can urea, or enhanced urea products be placed in-furrow.

Methods of early-season nitrogen applications

If the starter fertilizer can’t be “spiked” with urea to add extra N, how can the necessary 20 to 40 pounds of N be applied? Subsurface banding (knifing) of N as either anhydrous ammonia, liquid UAN, or dry product will result in the greatest N use efficiency by the wheat crop. This is especially true for no-till wheat production.

If knifed N applications are not used, the next best application method would be surface banding (dribbling) of UAN solution in streams on 15- to 18-inch centers. Broadcasting urea, ammonium nitrate, or UAN applications are not generally as efficient as subsurface banding, but they are often the best choice due to equipment, logistics, or weed management considerations. Broadcast applications of N will have the most consistent performance if followed by light incorporation, precipitation, or irrigation.

Direct seed placement of nitrogen

When placing starter fertilizer in direct contact with wheat seed, producers should use the following guidelines:

The problem with placing urea-containing fertilizer with the seed is that urea is initially converted to ammonia and may be toxic to plant roots if the wheat seed is placed in direct contact with the fertilizer. Producers may hear of someone who has placed urea in direct seed contact and seemed to have no problems, but there are also many cases where urea-containing N fertilizers has injured the developing seedling and reduced or delayed emergence significantly. The risk of injury is greater in drier soils, at higher soil pH levels, and at higher N rates. High soil pH favors a higher concentration of ammonia as compared to ammonium as urea hydrolyzes. There is significant risk associated with placing urea-containing fertilizers in direct seed contact.

The chart below shows how soil texture affected the level of wheat germination when urea-N was applied with the seed in a K-State greenhouse study. The wheat was well watered in this study, but urea-N placed with the seed still reduced germination, especially in the sandy soil. The readings shown below were taken after 10 days. With the high rates of urea used in this study, it is possible that more damage to the seedlings would occur with time as the urea continues to hydrolyze into ammonia.

Field studies have also shown reduced wheat stands due to in-furrow placement of urea. Across 5 site­ years in western Kansas the placement of urea in-furrow has resulted in decreased stands at spring greenup compared to the control (Figure 2).

The stand reduction becomes especially noticeable at higher rate of N. One of the challenges of understanding the risk of seedling injury is that the magnitude of injury varies by field conditions an years. In some years very little reduction may be evident, even at higher rates of N, while in other years, stand reductions (and their associated impact on yield) is very evident. As an example at Tribune in 2017, reduction in stand caused by urea placement with seed, and their effect on yield were quite evident (Figures 3 and 4).

Stands were reduced 32 and 63% compared to the control when 30 and 60 lbs of N as urea were applied in-furrow (Figure 3). This resuled in yield reductions of 14 and 40%, respectively (Figure 4).

If you’d like to apply extra N directly in the seed furrow, one option is to use a controlled-release form of N, such as ESN. As shown in figure 4, at N application rates of 30 lbs/ac and less, where ESN-N was applied in-furrow, wheat yields were essentially the same as where the N was applied pre-plant, and higher compared to the same amount of N applied as urea. At the highest rate of application in the study, 60 lbs/ac, even ESN resulted in stand and grain yield reductions.

Also, air seeders that place the starter fertilizer and seed in a band an inch or two wide, or side band the fertilizer relative to the seed, provide some margin of safety because the concentration of the fertilizer and seed is lower in these diffuse bands. In this scenario, adding a little extra urea containing N fertilizers to the starter less likely to injure the seed – but it is still a risk.

Here is a great video by Dr. Haag.