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Laboratory evaluation of Liquid Calcium
Liquid calcium products have been around for a long time. The vast majority of these products are either a calcium chloride or chelated calcium base which is now commonly found with the addition of a humic acid, microbial, or micronutrient. Many of these make promises such as “raises your soil pH with natural, regenerative, liquid calcium fertilizers that correct soil pH quickly, efficiently, and affordably!”. From a soil chemistry aspect the promise of adding 3 to 5 gallons of a Ca solution, which is approximately 10% Ca, will raise the soil pH is impossible on a mass balance approach. In this I mean that to increase the pH of an acid soil {soil pH is the ratio of hydrogen (H) and hydroxide (OH) in the soil, and having an acid soil means the concentration of H is greater than that of OH} requires a significant portion of the H+ that is in solution and on soil particle to be converted to OH, or removed from the system entirely.
The blog below walks through the full chemical process of liming a soil but in essence to reduce the H+ concentration we add a cation (positively charged ion) such as Ca or magnesium (Mg) which will kick the H+ of the soil particle and a oxygen (O) donator such as CO2 with ag lime or (OH)2 which is in hydrated lime. Each of these O’s will react with two H’s to make water. And with that the pH increases.
However regardless of the chemistry, there is always a lot of discussion around the use of liquid calcium Therefore we decided to dig into the question with both field and laboratory testing. This blog will walk through the lab portion.
This was a laboratory incubation study. The objective was to evaluation the impact of the liquid Ca product (LiqCa**) on the soil pH, buffer capacity, Ca content and CEC of two acidic soils. LiqCa was applied at three rates to 500 g of soil. The three rates were equivalent to 2, 4, and 6 gallon per acre applied on a 6” acre furrow slice of soil. One none treated check and two comparative products were also applied. HydrateLime (CaO) as applied at rate of Ca equivalent to the amount of Ca applied via LiqCa, which was approximately 1.19 pounds of Ca per acre. Also AgLime (CaCO3) was applied at rates equivalent to 1, 2, and 4 ton effective calcium carbonate equivalency (ECCE). The Ag lime used in the study had a measured ECCE of 92%. The two soils selected for both acidic but had differing soil textures and buffering capacities. The first LCB, had an initial soil pH (1:1 H2O) of 5.3 and a texture of silty clay loam and Perkins had a initial pH of 5.8 and is a sandy loam texture. Both soils had been previously collected, dried, ground, and homogenized. In total 10 treatments were tested across two soils with four replications per treatment and soil.
Project protocol, which has been used to determined site specific liming and acidification rates, was to apply the treatments to 500 grams of soil. Then for a period of eight weeks this soil wetted and mixed to a point of 50% field capacity once a week then allowed to airdry and be mixed again. At the initiation and every two weeks after soil pH was recorded from each treatment. The expectation is that soil pH levels will change as the liming products are impacting the system and at some point, the pH reaches equilibrium and no longer changes. In this soil that point was week six however the trail was continued to week eight for confirmation. See Figures 1 and 2.
ANOVA Main effect analysis showed that Soil was not a significant effect so therefore both soils were combined for further analysis. Figure 3 shows the final soil pH of the treatments with letters above bars representing significance between treatments. In this study all treatments were significantly greater than the check with exception of LiqCal 2 and CaO 6. Neither LiqCal or CaO treatments reached the pH level of Aglime, regardless of rate.
Summary
The incubation study showed that application of LiqCal at a rate of 4 and 6 gallons per acre did significantly increase the soil pH by 0.1 pH units and 6 gallons per acre increased the Buffer index above the check by 0.03 units. Showing the application of LiqCal did impact the soil. However the application of 1 ton of Ag lime resulted in significantly great increase in soil pH, 1.0 units by 8 weeks and a buffer index change of 0.2 units. The Aglime 1 was statistically greatly than all LiqCal treatments. Ag lime 2 and 4 were both statistically greater than Ag lime 1 with increasing N rate with increasing lime rate. Given the active ingredient listed in LiqCal is CaCl, this result is not unexpected. Ag lime changes pH by the function of CO3 reacting H+ in large quantities. In a unsupported effort a titration was performed on LiqCal, which show the solution was buffered against pH change. However it was estimated that a application of approximately 500 gallons per acre would be needed to sufficiently change the soil pH within a 0-6” zone of soil.
Results of the field study.
https://osunpk.com/2025/06/02/field-evaluation-of-lime-and-calcium-sources-impact-on-acidity/
Take Home
The application of a liquid calcium will add both calcium and chloride which are plant essential nutrients and can be deficient. In a soil or environment suffering from Cl deficiency specifically I would expect an agronomic response. However this study suggest there is no benefit to soil acidity or CEC with the application rates utilized (2, 4, and 6 gallon per acre).
** LiqCal The product evaluated was derived from calcium chloride. It should be noted that since the completion of the study this specific product used has changed its formulation to a calcium chelate. This change however would not be expected to change the results as the experiment did include a equivalent calcium rate of calcium oxide.
Other articles of Interest
https://extension.psu.edu/beware-of-liquid-calcium-products
https://foragefax.tamu.edu/liquid-calcium-a-substitute-for-what/
Any questions or comments feel free to contact me. b.arnall@okstate.edu
Nitrogen and Sulfur in Wheat
Brian Arnall, Precision Nutrient Management Specialist
Samson Abiola, PNM Ph.D. Student.
Nitrogen timing in wheat production is not a new topic on this blog, in-fact its the majority. But not often do we dive into the application of sulfur. And as it is top-dressing season I thought it would be a great opportunity to look at summary of a project I have been running since the fall of 2017 which the team has call the Protein Progression Study. The objective was to evaluate the impact of N and S application timings on winter wheat grain yield and protein. With a goal of looking at the ratio of the N split along with the addition of S and late season N and S, in such a way that we could determine BMP for maximizing grain yield and protein.
My work in the past has shown two things consistently, that spring N is better on the average and S responses have been limited to deep sandy soils in wet years. Way back when (2013) on farm response strips showed high residual N at depth and no response to S. https://osunpk.com/2013/06/28/response-to-npks-strips-across-oklahoma/. But there has been a lot of grain grown since that time expectations are that we should/are seeing an increase in S response. In fact Kansas State is seeing more S response, especially in the well drained soils in east half of the state.
Some KSU Sulfur works.
https://www.ksre.k-state.edu/news/stories/2022/04/video-sulfur-deficiency-in-wheat.html
https://eupdate.agronomy.ksu.edu/article/sulfur-deficiency-in-wheat-364-1
Click to access sulphur-in-kansas-plant-soil-and-fertilizer-considerations_MF2264.pdf
So the Protein Progression Project was established in 2017 and where ever we had space we would drop in the study. So in the end across six seasons we had 13 trials spread over five locations. Site-years varied by location: Chickasha (2018-2022), Lake Carl Blackwell (2018-2023), Ballagh (2020), Perkins (2021), and Caldwell (2021).
First lets just dive into the the N application were we looked at 100% pre vs 50-50 split and 25-75 split (Table 2.) Based upon the wealth of previous work https://osunpk.com/2022/08/26/impact-of-nitrogen-timing-2021-22-version/, its not much of a surprise that split application out preformed preplant and that having the majority applied in-season tended to better grain yields and protein values.
This next table is were things get to be un-expected. While the data below is presented by location, we did run each site year by itself. In no one site year did S statistically, or numerically increase yield. As you can see in Table 2 below, the only statistical response was a negative yield response to S. And you can not ignore the trend that numerically, adding S had consistently lower yields. Even more surprising was the same trend was seen in Protein.
One aspect of Protein Progression trials were that while 0-6″ soil test S tended to be low. We would often find pretty high levels of S when we sampled deeper, especially when there was a clay increase with depth. Sulfur tends to be held by the clay in our subsoil. We are also looking at better understanding the relationship between N and S. In fact a review article published in 2010 discussed that the N and S ratio can negative influence crop production when either one of the elements becomes un-balanced. For example we are seeing more often in corn that when N is over applied we can experience yield loss, unless we apply S. Meaning at 200 lbs of N we make 275 BPA, at 300 N lbs we make 250, but 300 N plus 20 S we can make 275 again. Part of the rationale is that excessive N limits S mineralization. On the flip side if S is applied while N is deficient and yield decrease could be experienced. Maybe that is what we are seeing in this date. Either way, this data is why the Precision Nutrient Management program is spending a fair amount of efforts in understanding the N x S relationship in wheat (which we are looking at milling quality also) and corn.
A quick dive into increasing protein with late N applications. At three of the five location GPC was significantly increased with Late N. In most cases the anthesis (flowering) application was the highest with exception of Caldwell. We will have another blog coming out in a month that digs into anthesis applied N at a much deeper level, looking at source, nozzle and droplet sizes.
Looking at this study in a vacuum we can say that it probably best to split apply your N and that in central and northern Ok the addition of S in rainfed wheat doesn’t offer great ROI. If I look at the whole picture of all my work and experience I would offer this. For grain only wheat, the majority if not all N should be applied in-season sometime between green up and two weeks after hollow stem. I have had positive yield responses to S applied top-dress, but it has always been deep sandy soils and wet seasons. I have not have much is any response to S in heavier soil, especially if there is a clay increase in the two feet of profile. So my general S recommendation is 10 lbs in sandy soils and if you show low soil test S in heavier ground and you are trying to push grain yields, then you could consider the addition of S as a potential insurance. That said, I haven’t seen much proof of it.
Take Homes
* Split application of nitrogen resulted in higher grain yields and protein concentrations when compared to 100% preplant.
* Putting on 75% of the total N in-season tended to result in higher grain yields and protein concentrations when compared to 50-50 split.
* Adding 10 lbs of S topdress did not result in any increase in grain yield or protein.
A big Thanks to the collaborators providing on-farm locations for this project. Ballagh Family Farms, Turek Family Farms and Tyler Knight.
Citation. Jamal, A.,*, Y. Moon, M. Abdin. 2010 Review article. Sulphur -a general overview and interaction with nitrogen. AJCS 4(7):523-529 (2010). ISSN:1835-2707.
Any questions or comments feel free to contact me. b.arnall@okstate.edu
Down and Dirty with NPK 